Formation of Langasite-Type Crystals in Corresponding Glasses and Their Second-Order Optical Nonlinearities
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- TAKAHASHI Yoshihiro
- Department of Chemistry, Nagaoka University of Technology
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- SAITOH Kenta
- Department of Chemistry, Nagaoka University of Technology
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- BENINO Yasuhiko
- Department of Chemistry, Nagaoka University of Technology
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- FUJIWARA Takumi
- Department of Chemistry, Nagaoka University of Technology
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- KOMATSU Takayuki
- Department of Chemistry, Nagaoka University of Technology
Bibliographic Information
- Other Title
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- ガラスからのランガサイト型結晶の生成とそれらの二次光非線形性
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Abstract
Second-order optical nonlinearities for the langasite-type phases obtained by crystallization of corresponding glasses are clarified for the first time. It is confirmed that most of langasite-type crystalline phases can be formed by crystallization in the corresponding glasses without introducting of any impurity phases, e.g., the glasses with the stoichiometric composition of Ba3Ga2Ge4O14, BaGa4La2Ge2O14, Pb3Ga2Ge4O14, etc. We find that Pb3Ga2Ge4O14 and Pb3AlGaGe4O14 phases exhibited strong second-harmonic intensities of approximately 100 times as large as α-quartz by means of a powder technique, demonstrating that those langasite-type crystals are excellent nonlinear optical materials. It is also suggested that the octahedral site is one of keys for second-order optical nonlinearity in langasite-type crystals.
Journal
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 112 (1301), 61-64, 2004
The Ceramic Society of Japan
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Details 詳細情報について
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- CRID
- 1390001205249307392
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- NII Article ID
- 110002288164
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- NII Book ID
- AN10040326
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- ISSN
- 18821022
- 09145400
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- NDL BIB ID
- 6812747
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed