Titanocene-Catalyzed Reaction of Alkenes and Dienes with Alkyl Halides and Chlorosilanes.
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- Terao Jun
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
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- Kambe Nobuaki
- Department of Applied Chemistry, Faculty of Engineering, Osaka University
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New catalytic reactions for regioselective introduction of alkyl and/or silyl functionalities to alkenes and dienes are described. These reactions proceed efficiently under mild conditions by the use of Cp2TiCl2 as a catalyst in the presence of Grignard reagents. The present study would provide a prototype for the practical use of alkyl halides and chlorosilanes in transition metal-catalyzed reactions. In these reactions, ate complexes of titanocene play important roles as the active species. The scope and limitations, as well as reaction pathways, are discussed.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 59 (11), 1044-1051, 2001
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205276869760
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- NII論文ID
- 10012285801
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- NII書誌ID
- AN0024521X
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- COI
- 1:CAS:528:DC%2BD3MXotlKnsL4%3D
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 5968729
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可