Preparation of Single Crystals under Hydrothermal Conditions
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- YANAGISAWA Kazumichi
- Research Laboratory of Hydrothermal Chemistry, Faculty of Science, Kochi University
Bibliographic Information
- Other Title
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- 水熱条件下での単結晶の合成
- Special Article: The 59th CerSJ Awards for Academic Achievements: Preparation of Single Crystals under Hydrothermal Conditions
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Abstract
The capability of preparing carbonates and hydroxides that decompose in air at high temperatures is one of the advantages of hydrothermal reactions as a preparation technique for inorganic materials. In this study, new hydrothermal techniques to prepare single crystals of calcite (carbonate) and hydroxyapatite (hydroxide) were described. For hydrothermal crystal growth of calcite, organic salt solutions were used as a mineralizer for the first time and a solution of ammonium acetate was found to be an excellent mineralizer to obtain high growth rate under mild hydrothermal conditions. Single crystals of hydroxyapatite were prepared from chlorapatite single crystals by ion exchange in alkaline solutions under hydrothermal conditions. The transformation mechanism was explained by dissolution and precipitation of clusters.<br>
Journal
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 113 (1321), 565-572, 2005
The Ceramic Society of Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001205277257600
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- NII Article ID
- 110002292384
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- NII Book ID
- AN10040326
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- ISSN
- 18821022
- 09145400
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- NDL BIB ID
- 7468445
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed