Paterno-Buechi[2+2] Photocycloaddition Reactions of Silyl Ketene Acetals: Controlling Factors on the Regio- and Stereoselectivity in the Oxetane Formations.
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- Abe Manabu
- Department of Materials Chemistry, Graduate School of Engineering, Osaka University
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- Nojima Masatomo
- 大阪大学大学院工学研究科
Bibliographic Information
- Other Title
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- シリルケテンアセタール類のPaterno‐Buechi型光[2+2]環化付加反応 オキセタンの位置および立体選択性に及ぼす因子
- シリルケテンアセタールルイ ノ Paterno Buchiガタ ヒカリ 2 2 カンカ フカ ハンノウ オキセタン ノ イチ オヨビ リッタイ センタクセイ ニ オヨボス インシ
- <I>Controlling Factors on the Regio- and Stereoselectivity in the Oxetane Formations</I>
- オキセタンの位置および立体選択性に及ぼす因子
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Abstract
We have explored the regio- and stereoselectivity in the [2+2] photocycloaddition, so-called Paternò-Büchi reaction, of silyl ketene acetals with carbonyl compounds. The structures of the intermediates, i.e. radical cation, exciplex, 1, 4-biradical, have been proposed to be an important factor of controlling the selectivities. This account provides the useful information on the selective synthesis of oxetane derivatives.
Journal
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- Journal of Synthetic Organic Chemistry, Japan
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Journal of Synthetic Organic Chemistry, Japan 59 (9), 855-865, 2001
The Society of Synthetic Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001205277478784
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- NII Article ID
- 10012287033
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- NII Book ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL BIB ID
- 5905509
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed