有機合成に用いられる金属化合物の合成と性質　　Ｃｕ　　Ｐｒｅｐａｒａｔｉｏｎ　ｏｆ　ｃｏｐｐｅｒ　ｃｏｍｐｏｕｎｄｓ　ｕｔｉｌｉｚｅｄ　ｆｏｒ　ｏｒｇａｎｉｃ　ｓｙｎｔｈｅｓｅｓ　（有機合成に利用される銅化合物の製造）

DOI Web Site

Bibliographic Information

Other Title
  • Cu

Search this article

Abstract

Lithium dialkylcopper, cuprate, is prepared in situ by treating a suspension of cuprous iodide in ether or THF with 2 equivalent of alkyllithium. Anhydrous cupric chloride is prepared by heating commercially available CuCl2·2H2O at 120°C for several hours. Cuprous oxide is prepared by heating commercially available Cu2O in vacuo at 6070°C for several hours. Copper (I) carbonyl cation is generated by treating cuprous oxide in sulfuric acid with 1 atm. of carbon monoxide. Active copper powder is prepared by reducing cupric sulfate in water with zinc powder under nitrogen gas. Copper (I) tert-butoxide is prepared by reacting anhydrous cuprous chloride with lithium tert-butoxide in THF. Copper (I) tert-butoxide is thermally stable under nitrogen and purified by sublimation at 170°C/1 mmHg. Copper (I) triflate · (benzene) 1/2 complex is prepared by heating cuprous oxide with trifluoromethanesulfonic acid anhydride in benzene at reflux. Some synthetic reactions using the copper compounds thus prepared are also described.

Journal

Keywords

Details 詳細情報について

Report a problem

Back to top