Effects of High Magnetic Field on Organic Reactions.
-
- TANIMOTO Yoshifumi
- Faculty of Science, Hiroshima University
-
- FUJIWARA Yoshihisa
- Faculty of Science, Hiroshima University
Bibliographic Information
- Other Title
-
- 強磁場中の有機化学
- キョウジバチュウ ノ ユウキ カガク
Search this article
Abstract
Effects of high magnetic field (<14 T) on the primary process of organic photochemical reactions and related phenomena are reviewed. With increasing a magnetic field, lifetimes of triplet radical pairs in micellar solution and triplet biradicals in homogeneous solution increase significantly, reach their maximum values at ca. 2 T, and then decrease gradually up to 14 T. These results are interpreted in terms of the radical pair mechanism. The effects at low field are attributable to the reduction of spin transitions due to the isotropic and anisotropic hyperfine interaction. The inversion of the lifetime is attributable to the enhancement of spin relaxation induced by the anisotropic g-value.
Journal
-
- Journal of Synthetic Organic Chemistry, Japan
-
Journal of Synthetic Organic Chemistry, Japan 53 (5), 413-422, 1995
The Society of Synthetic Organic Chemistry, Japan
- Tweet
Keywords
Details 詳細情報について
-
- CRID
- 1390001205277729792
-
- NII Article ID
- 10001713463
-
- NII Book ID
- AN0024521X
-
- COI
- 1:CAS:528:DyaK2MXlslGiur8%3D
-
- ISSN
- 18836526
- 00379980
-
- NDL BIB ID
- 3614973
-
- Text Lang
- ja
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- Abstract License Flag
- Disallowed