Ca<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>-MgSiO<sub>3</sub>系の相関係
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- 佐多 敏之
- 熊本工業大学工業化学科
書誌事項
- タイトル別名
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- Phase Relation in the System Ca<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>-MgSiO<sub>3</sub>
- Phase Relation in the System Ca3 PO4 2
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Phase relations in the system tricalcium phosphate (3CaO⋅P2O5=C3P)-enstatite (MgO⋅SiO2=MS) have been investigated in the temperature range 1100 to 1600°C by means of the quenching method. C3P takes β-type (whitrockite) in a wide region by dissolution of MgO, and diopside (d) appeared in the composition range more than 40mass% C3P by a reach in between MgSiO3 and liberated CaO. The enstatite transfers to iron-free pigeonite (pi) by taking CaO in an MS-rich region, where pi coexists with protoenstatite, MgSiO3 (pr). Primary crystals which appeared in a wide region are β-C3P and pi, and primary diopside appears in a narrow region at a minimum temperature (1265-1305°C). In the subsolidus region below 1245°C, β-C3P coexists with d, pi or pi-pr mixture. The system is not binary and it should be discussed from the ternary system C3P-M-S and the quaternary system C3P-CMS2-MS-S.
収録刊行物
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- Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
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Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌) 104 (1210), 490-496, 1996
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390001205278627072
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- NII論文ID
- 110002291500
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- NII書誌ID
- AN10040326
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- ISSN
- 18821022
- 09145400
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- NDL書誌ID
- 3967126
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- データソース種別
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- JaLC
- NDL
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