書誌事項
- タイトル別名
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- Occurrence of Bimodal Pore Structure and Leaching Process in the Preparation of Porous Glass from Fluorine Containing Sodium Borosilicate Glass
- Occurrence of Bimodal Pore Structure an
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Leaching process in the preparation of porous glass from fluorine containing sodium borosilicate glass was intensively investigated under different conditions of phase-separation temperature, the thickness of specimens and the amount of acid leaching solution. Techniques employed are pore size distribution measurements and SEM observation with focusing on the leaching of SiO2 component from the B2O3-rich phase. The pores formed in the inner part of specimens, after being treated with 0.5mol/l sulfuric acid solution of 200ml/(g-specimen) at 92±1°C for 0.5h, had a smaller size than those formed in the surface layer of specimens. Those smaller pores contained a larger amount of silica-gel which precipitated from the B2O3-rich phase in the leaching process. This is the cause why a bimodal pore structure was inevitably obtained through the course of leaching: the silica-gel was removable by leaching with a larger amount of acid solution for a prolonged time. In the early stage of leaching process, the dissolution of the B2O3-rich phase proceeds, forming smaller pores with residual silica-gel, and the silica-gel is subsequently removed from the smaller pores resulting in enlargement. This diffusion-controlled process proceeds from the surface of the specimen to its inner part, indicating that a thin specimen is effective to accomplish the complete removal of the silica-gel with a minimum amount of the leaching solution.
収録刊行物
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- Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
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Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌) 104 (1207), 179-184, 1996
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390001205278868864
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- NII論文ID
- 110002291335
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- NII書誌ID
- AN10040326
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- ISSN
- 18821022
- 09145400
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- NDL書誌ID
- 3936661
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- データソース種別
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- JaLC
- NDL
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