Recent Advances in the Synthesis of Optically Active .ALPHA.-Amino Acids.

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  • OGURA Katsuyuki
    Department of Applied Chemistry, Faculty of Engineering, Chiba University
  • INABA Takashi
    Department of Applied Chemistry, Faculty of Engineering, Chiba University

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  • 光学活性アミノ酸合成の最近の進歩
  • コウガク カッセイ アミノサン ゴウセイ ノ サイキン ノ シンポ

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To date, there have been explored many methods for synthesizing optically active α-amino acids. This review describes recent development of these synthetic methods from a viewpoint of three types of asymmetric bond formation at the α-carbon of α-amino acids : (i) α-alkylation of glycine and its synthetic equivalents ; (ii) α-amination of carboxylic acids ; and (iii) α-carboxylation of amines.

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