Synthesis of Peroxo-Modified Anatase Sol from Peroxo Titanic Acid Solution

DOI Web Site Web Site 22 Citations 15 References

Bibliographic Information

Other Title
  • ペルオキソチタン酸溶液からのペルオキソ修飾されたアナターゼゾルの合成
  • Synthesis of Peroxo-Modified Anatase So

Search this article

Description

A peroxo titanic acid (PTA) solution has been prepared by mixing titanic acid wet gel and hydrogen peroxide solution. The PTA solution was a neutral, transparent, stable liquid. The PTA crystallized to form an anatase phase after calcination at a temperature above 250°C. When the PTA solution was autoclaved at a temperature above 100°C for 6h, it changed to a sol containing anatase crystals less than 20nm in diameter. Aggregation occurred after autoclaving at a temperature above 120°C. When the PTA solution was heated to 100°C, it was translucent and stable in spite of containing ultrafine anatase crystals (9nm in diameter). It was deduced that the surfaces of anatase crystals are modified by the peroxo groups.

Journal

Citations (22)*help

See more

References(15)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top