PREPARATION AND CHARACTERIZATION OF CALCIUM PHOSPHATE PARTICLES FROM FORCED HYDROLYSIS OF Ca(OH)2-TRIPHOSPHATE-K2S2O8 MIXED SOLUTION
-
- Kandori Kazuhiko
- School of Chemistry, Osaka University of Education
-
- Matsui Naoko
- School of Chemistry, Osaka University of Education
書誌事項
- タイトル別名
-
- PREPARATION AND CHARACTERIZATION OF CALCIUM PHOSPHATE PARTICLES FROM FORCED HYDROLYSIS OF Ca(OH)<SUB>2</SUB>-TRIPHOSPHATE-K<SUB>2</SUB>S<SUB>2</SUB>O<SUB>8</SUB> MIXED SOLUTION
この論文をさがす
説明
The effects of potassium peroxodisulfate (K2S2O8) on the formation of calcium phosphate particles produced by aging Ca(OH)2 and sodium triphosphate (sodium tripolyphosphate, Natpp: Na5P3O10) mixed solution at 100∼160°C for 18 h were examined. Spherical and monodispersed particles were produced at low K2S2O8 concentration ([K2S2O8]) region ([K2S2O8]≤4 mM) and their size was increased by increase in [K2S2O8]. On the contrary, fine irregular particles were produced at [K2S2O8]≥6 mM. The monodispersed spherical particles produced at [K2S2O8]≤4 mM were amorphous, though small irregular particles produced at [K2S2O8]≥6 mM were poorly crystallized calcium pyrophosphates (β-Ca2P2O7). The Ca/P atomic ratios of these samples were 0.79∼0.90, fairly closed to the Ca/P atomic ratio of 1.0 for β-Ca2P2O7. A high adsorption selectivity of H2O was observed on amorphous monodispersed spherical particles. On the other hand, the β-Ca2P2O7 particles with small amounts of hydrated H2O produced at [K2S2O8]≥6 mM exhibited no selective adsorption of H2O. With increase in the aging temperature, small numbers of transparent balloon-like hollow spheres were obtained at 120∼140°C. However, the fraction of hollow spheres was less than 5%. Aging above 150°C, no balloon-like hollow sphere was precipitated but finally calcium hydroxyapatite (Ca10(PO4)6(OH)2, Hap) particles with small rod-like shape could be precipitated. These Hap particles produced at 150 and 160°C did not exhibit selective adsorption of H2O.
収録刊行物
-
- Phosphorus Research Bulletin
-
Phosphorus Research Bulletin 27 (0), 37-44, 2012
日本無機リン化学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390001205286294272
-
- NII論文ID
- 130004951159
-
- COI
- 1:CAS:528:DC%2BC38XhtlarsbfM
-
- ISSN
- 18822363
- 09184783
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可