Nitridation of δ-alumina to aluminum nitride under a flow of ammonia and its mechanism
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- KIM Jun-Kwang
- School of Chemical Engineering, College of Engineering, Yeungnam University
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- JUNG Woo-Sik
- School of Chemical Engineering, College of Engineering, Yeungnam University
書誌事項
- タイトル別名
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- Nitridation of δ-alumina to aluminum nitride under a flow of ammonia and its mechanism
- Nitridation of d alumina to aluminum nitride under a flow of ammonia and its mechanism
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Nanosized δ-alumina (δ-Al2O3) powders were calcined at various temperatures under a flow of ammonia (NH3) passing over a carbon black-containing crucible. The nitridation process of δ-Al2O3 to aluminum nitride (AlN) was monitored by powder X-ray diffraction, infrared (IR) spectroscopy, and 27Al magic-angle spinning nuclear magnetic resonance spectroscopy. δ-Al2O3 began to be converted to AlN at 1150°C without δ-α alumina transformation and the conversion was completed at 1300°C for 5 h. The IR spectra of the gases evolved during the nitridation revealed the inclusion of NH3, CH4, HCN, and CO gases. Results on the calcination of δ-Al2O3 under a flow of acetonitrile diluted in argon indicated that HCN is involved in the nitridation reaction of δ-Al2O3.
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 119 (1389), 351-354, 2011
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390001205288224128
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- NII論文ID
- 130000662437
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- NII書誌ID
- AA12229489
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- ISSN
- 13486535
- 18820743
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- NDL書誌ID
- 11057940
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 使用不可