Study of modification on alumina surface by using of organosilicon polymer
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- KITA Ken’ichiro
- National Institute of Advanced Industrial Science and Technology (AIST)
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- KONDO Naoki
- National Institute of Advanced Industrial Science and Technology (AIST)
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- HYUGA Hideki
- National Institute of Advanced Industrial Science and Technology (AIST)
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- IZUTSU Yasuhisa
- Stereo Fabric Research Association
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- KITA Hideki
- National Institute of Advanced Industrial Science and Technology (AIST)
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This paper describes a novel experiment on surface modification for alumina plates. Polycarbosilane (PCS), an organosilicon polymer, was used in this experiment as a precursor. Tiny cracks on an alumina surface caused by grain boundaries and introduced by rough grinding were filled by PCS, and PCS was transformed into silicon oxycarbide (SiCO, silicon carbide including several mass percents of oxygen) by thermal oxidation curing at 453 K and pyrolysis at 1273 K. Moreover, Al6Si2O13 (mullite) layer was made from alumina and SiCO and prevented exfoliation of the alumina and SiCO during pyrolysis. In addition, the wettability between samples and molten aluminum was investigated in order to make sure the effect of surface modification. This experiment confirms that surface modification of alumina with a SiCO membrane can be successfully.
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 119 (1389), 378-381, 2011
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390001205288403584
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- NII論文ID
- 130000662443
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- NII書誌ID
- AA12229489
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- ISSN
- 13486535
- 18820743
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- NDL書誌ID
- 11058014
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可