Organometallic Multinuclear Sandwich Complexes
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- Murahashi Tetsuro
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University PRESTO-JST
Bibliographic Information
- Other Title
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- サンドイッチ型多核金属錯体の創製
- サンドイッチガタ タカク キンゾク サクタイ ノ ソウセイ
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Abstract
Recent development in the chemistry of multinuclear sandwich compounds is summarized in this article. Existence of stable multinuclear sandwich complexes was proven through isolation and structural characterization of a series of multinuclear palladium sandwich complexes. One-dimensional multinuclear sandwich complexes in which two parallel unsaturated hydrocarbon ligands flank a Pd chain were prepared in a size selective manner. Moreover, two-dimensional multinuclear sandwich complexes which contain a Pd sheet between two unsaturated hydrocarbon ligands were also prepared by employing mono- and polycyclic aromatic hydrocarbons as the facially coordinated ligands. Unique behavior of the multinuclear sandwich compounds such as the sliding of the bridging ligands was also revealed. These findings lead to new aspects in the structures of organotransition metal compounds.
Journal
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 51 31-40, 2008
Japan Society of Coordination Chemistry