Effects of Coordination Environments upon Emissive Silver(I) Complexes
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- Tsuge Kiyoshi
- Graduate School of Science and Engineering, University of Toyama
Bibliographic Information
- Other Title
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- 配位子からみた発光性銀(I)錯体
- 配位子からみた発光性銀(1)錯体
- ハイイシ カラ ミタ ハッコウセイギン 1 サクタイ
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Abstract
Recent development of emissive transition metal complexes involves synthesis of various copper(I) and gold(I) complexes that reveals attracting emissive nature of monovalent group 11 metal complexes. Although the development of silver(I) complexes has not been expanding so rapidly as gold(I) and copper(I) complexes, a considerable number of researches reporting the emissive properties of silver(I) complexes appeared in this decade. In this article, emissive silver(I) complexes, together with the copper(I) or gold(I) congeners if available, are classified by their coordination environments to achieve a general idea to control the emissive properties by ligands and structures. π-Donating/accepting properties and available low-lying π* orbitals and metal-metal interactions appear to be important for phosphorescent silver(I) complexes.
Journal
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 56 (0), 24-40, 2010
Japan Society of Coordination Chemistry