New Development on the Origin of Circular Dichrosim for Chiral Octahedral Metal Complexes
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- Akitsu Takashiro
- Department of Chemistry, Faculty of Science, Tokyo University of Science
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- Yamazaki Atsuo
- Department of Chemistry, Faculty of Science, Tokyo University of Science
Bibliographic Information
- Other Title
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- キラル八面体型金属錯体のＣＤの起源の新展開
- New Development on the Origin of Circular Dichroism for Chiral Octahedral Metal Complexes
Abstract
Time-dependent density functional theory has been successfully applied to analyze circular dichroism spectra of Δ- or Λ- octahedral metal complexes with bidentate ligands containing both s- and p-orbitals. Rotatory strengths associated with electronic transitions not only d-d transition but also ligand to metal charge transfer (LMCT) and π-π* transitions can be interpreted in terms of transition moments for excitations of metal complexes containing ligand moieties within a qualitative framework.
Journal
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 55 78-79, 2010
Japan Society of Coordination Chemistry
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Keywords
Details 詳細情報について
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- CRID
- 1390001205297512960
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- NII Article ID
- 130000322472
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- ISSN
- 18831737
- 18826954
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- Text Lang
- ja
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed