Photophysical Properties of Transition Metal Complexes under Rigid Environments
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- Ito Akitaka
- Department of Chemistry, Graduate School of Science, Osaka City University
Bibliographic Information
- Other Title
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- リジッドな環境下における遷移金属錯体の光化学物性
- リジッド ナ カンキョウ カ ニ オケル センイ キンゾク サクタイ ノ コウカガク ブッセイ
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Abstract
Recent research trends on the photophysical properties of transition metal complexes under rigid environments are overviewed. Since the transition metal complexes are often introduced into rigid environments in photochemical applications/devices such as organic light-emitting diodes (OLEDs) and dye-sensitized solar cells (DSSCs), the rigid medium effects on the excited-state characteristics of the complexes are still worth studying. Crystalline solids, frozen glasses and polymer matrices are picked up as examples of rigid environments. Under these conditions, the metal complexes show characteristic photophysical properties which differ from those in fluid solution owing to the rigidity of the surrounding environments.
Journal
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 63 (0), 46-48, 2014
Japan Society of Coordination Chemistry