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- 藤田 誠
- 東京大学大学院工学系研究科
書誌事項
- タイトル別名
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- Molecular Self-Assembly Based on Coordination Chemistry
- Award Accounts 配位結合を活用した自己組織化の化学
- Award Accounts ハイイ ケツゴウ オ カツヨウ シタ ジコ ソシキカ ノ カガク
この論文をさがす
抄録
Molecular self-assembly has recently undergone on explosive development, making possible the synthesis of many fascinating and complex structures using only relatively simple procedures. Over the last two decades, we have been showing that the simple combination of palladium's square planer geometry (a 90 degree coordination angle) with pyridine-based bridging ligands gives rise to the quantitative self-assembly of nano-sized, discrete organic frameworks. Representative and early examples in this field include square molecules (1990), linked-ring molecules (1994), cages (1995), tubes (1999), capsules (1999), and spheres (2004) that are self-assembled from simple and small components. By networking the discreet frameworks, we have also developed porous coordination networks (1994). In this article, we will disclose the structure of these self-assemblies as well as the chemistry of self-assembled “space” created in the void of the assemblies, where new chemical and physical properties of enclosed molecules are exhibited.
収録刊行物
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 57 (0), 13-29, 2011
錯体化学会