-
- 徂徠 道夫
- 大阪大学
書誌事項
- タイトル別名
-
- Molecular Thermodynamics for Functional Metal-Complexes
抄録
Better understanding of materials should be achieved by complementarily employing experimental techniques which lead to either microscopic or macroscopic aspect. The specific characteristic of thermodynamics is the absence of any selection rule or selectivity. This makes a sharp contrast with various spectroscopies in which particular nuclide and/or particular modes are selectively sensed. This review demonstrates calorimetric investigations of spin-spin interaction in transition-metal complexes and the phase transitions occurring in molecule-based materials in which electrons are directly involved. Important roles played by molecular thermodynamics are illustrated for the following subjects: (i) Spin-spin interactions in tri-nuclear metal-complex, (ii) ferromagnetic phase transition in molecule-based magnets, (iii) determination of structure in a low-dimensional assembled-metal complex, (iv) change of electronic state due to molecular motion in an organometallic compound, (v) phase transitions due to spin-crossover phenomena, (vi) phase transition due to intramolecular electron transfers in mixed-valence complexes, and (vii) phase transition due to thermochromic phenomena. Since a change in the electronic state is strongly coupled with a change in the lattice, the transition mechanisms always include interplays with various molecular motions in the lattice.
収録刊行物
-
- Bulletin of Japan Society of Coordination Chemistry
-
Bulletin of Japan Society of Coordination Chemistry 61 (0), 17-37, 2013
錯体化学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390001205298684032
-
- NII論文ID
- 130004543352
-
- ISSN
- 18831737
- 18826954
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可