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- 三方 裕司
- 奈良女子大学理学部化学生命環境学科
書誌事項
- タイトル別名
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- Fluorescent Detection of Metal Ions and Pyrophosphate with TQEN-Based Quinoline Derivatives
- TQEN コッカク オ キバン ト スル キノリン ユウドウタイ オ モチイタ キンゾク イオン オヨビ ピロリンサン ノ ケイコウ ケンシュツ
この論文をさがす
抄録
<p>Fluorescent detection of specific metal ions with organic ligands is an attractive subject in coordination chemistry. This account summarizes the evolution history of fluorescent metal sensor TQEN (N,N,N’,N’-tetrakis(2-quinolylmethyl)ethylenediamine), which is a TPEN (N,N,N’,N’-tetrakis(2-pyridylmethyl)ethylenediamine)-based hexadentate ligand responding to zinc and cadmium ions. The dim fluorescence intensity and insufficient Zn/Cd selectivity of TQEN have been effectively improved by changing the ligand structure. Mercury and pyrophosphate ions are also targeted by rational modification of the molecule.</p>
収録刊行物
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- Bulletin of Japan Society of Coordination Chemistry
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Bulletin of Japan Society of Coordination Chemistry 68 (0), 3-15, 2016
錯体化学会