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- MITOGUCHI Hirozo
- Faculty of Technology, Hiroshima University
Bibliographic Information
- Other Title
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- 5-および3-ニトロアセナフテンの合成
- 5- オヨビ 3-ニトロアセナフテン ノ ゴウセイ
- Nitration of Acenaphthene and Its Derivatives (Part I)
- アセナフテンおよびその誘導体のニトロ化 (第1報)
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Abstract
The nitration method of aromatic compounds using a mixture of metal nitrates and acetic anhydride, commonly called the Menke method, was applied for the synthesis of 5- and 3-nitroacenaphthenes. 5-Nitroacenaphthene was obtained in a yield of ca. 90% even at 30°C, when an amount of metal nitrate equivalent to the acenaphthene dissolved in acetic anhydride was added. However, 3-nitroacenaphthene was formed together with the 5-isomer by the reversed treatment at -10°C in a yield of 18%. Of various metal nitrates tested, cupric and zinc nitrates proved most satisfactory.
Journal
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- Journal of Synthetic Organic Chemistry, Japan
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Journal of Synthetic Organic Chemistry, Japan 27 (7), 642-647, 1969
The Society of Synthetic Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001205310886912
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- NII Article ID
- 130000931322
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- NII Book ID
- AN0024521X
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- COI
- 1:CAS:528:DyaF1MXltFalurw%3D
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- ISSN
- 18836526
- 00379980
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- NDL BIB ID
- 8466731
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed