Application of Characteristic Electroreactions to Organic Syntheses

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  • NONAKA Tsutomu
    Department of Electronic Chemistry, Graduate School at Nagatsuta, Tokyo Institute of Technology
  • FUCHIGAMI Toshio
    Department of Electronic Chemistry, Graduate School at Nagatsuta, Tokyo Institute of Technology

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  • 特徴的な電解反応の有機合成への応用
  • トクチョウテキ ナ デンカイ ハンノウ ノ ユウキ ゴウセイ エ ノ オウヨウ

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Abstract

This review is organized under the following headings with 440 references.<BR>1. Generation and reactions of reactive intermediates.<BR>1.1. Carbon species. 1.2. Nitrogen species. 1.3. Oxygen species. 1.4. Others.<BR>2. Reactions of organic hetero atoms.<BR>2.1. Nitrogen. 2.2. Sulfur. 2.3. Phosphorus and others.<BR>3. Formation and reactions of organometallic compounds.<BR>3.1. Formation of metallic compounds employing electrodes as a metal source.<BR>3.2. Conversion of metallic compounds to other metallic compounds. 3.3. Formation of nonmetallic compounds from metallic compounds.<BR>4. Bimolecular reactions.<BR>4.1. Dimerization. 4.2. Cyclization. 4.3. Ring expansion and contraction.<BR>5. Stereochemistry.<BR>5.1. Stereoselective and stereospecific reactions. 5.2. Asymmetric reactions and asymmetric syntheses.<BR>6. New type reactions.

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