書誌事項
- タイトル別名
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- Selective Bromination of Polyenes with TBCO (2, 4, 4, 6-tetrabromocyclohexadienone)
- TBCO 2 4 4 6 tetrabromocyclohexadienone
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説明
In connection with a program directed toward the biogenetic type synthesis of bromine containing terpenoids, we have searched a new reagent system and found that 2, 4, 4, 6-tetrabromocyclohexadienone (TBCO) is effective for bromination of polyenes. Reaction fashion of TBCO can be divided into four types. 1. Dibromination, , 2. Brominative cyclization, 3. Bromo etherification of polyene alcohol and ketone, and 4. Bromohydrin formation in the presence of ROH. Details are described.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 35 (6), 491-496, 1977
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205310938112
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- NII論文ID
- 130000924532
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 1832810
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可