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- 青木 伸
- 東京理科大学薬学部
書誌事項
- タイトル別名
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- Design and Synthesis of New Supramolecular Complexes by Molecular Assembly of Multinuclear Zinc (II) Complex Modules
- タカク アエン 2 サクタイ モジュール ノ シュウセキカ ニ ヨル シン キノウセイ チョウブンシ ノ セッケイ ト ゴウセイ
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説明
In natural biological systems, Zn2+ ion is found used as a structural factor, a catalytic factor, and a cocatalytic factor in many enzymes and proteins. In this article, we describe the design and synthesis of two classes of three-dimensional supramolecular complexes that are formed by assembly of multinuclear Zn2+ complex modules. The first group includes cuboctahedral capsules and trigonal prisms, in which Zn2+ ions are 5-coordinated and work as structural factors. The other class includes a supramolecular luminescent sensor for inositol 1, 4, 5-triphosphate (IP3) and its achiral model compound, cis, cis-1, 3, 5-cyclohexanetriol triphoshate (CTP3), which is formed by Ru-templated assembly of dimeric Zn2+ complexes, where Zn2+ ions work as recognition factors for three phosphates. This knowledge will be useful in designing novel supramolecular complexes and their applications in bioinorganic chemistry, bioinorganic chemistry, and other related scientific fields.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 64 (6), 608-616, 2006
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205311060864
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- NII論文ID
- 10019174028
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 7988526
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可