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- 江藤 勝清
- 城大学工学部
書誌事項
- タイトル別名
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- Catalytic Dehydro-Condensation Reaction of Ethanol
- エタノール ノ セッショク ダツスイソ シュクゴウ ハンノウ 1
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説明
With an object of synthesis of n-butanol by condensation of ethanol, experiments on using of magnesia, zinc oxide, copper, and magnesia-copper mixture as catalyst have been carried out. Zinc oxide showed to be a good catalyst for dehydrogenation of ethanol and aldol condensation, but it showed a poor catalytic activity for reduction of aldol condensation product to n-butanol. Then the reaction products were a mixture of lower to higher aldehydes and the yield of n-butanol was extremely small. In the condensation of aldehyde, the copper catalyst accelerated strongly ester formation by the Tischenko reaction, but it showed a poor catalytic activity on reduction of crotonaldehyde to n-butanol. Then the main products were a mixture of esters. The magnesia catalyst showed the least activity for ethanol but it had the most selective activity for formation of n-butanol against above two. A coprecipitate of magnesia-copper catalyst could not maintain the merits of each and its activity was rather inferior than magnesia.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 21 (1), 61-67, 1963
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205311148544
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- NII論文ID
- 130000923200
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- NII書誌ID
- AN0024521X
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- COI
- 1:CAS:528:DyaF3sXktVaqsbs%3D
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 9213652
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- データソース種別
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- JaLC
- NDL
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