書誌事項
- タイトル別名
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- Metal Complexes-catalyzed Hydrolysis, Alcoholysis, and Hydroalkoxylation
- キンゾク サクタイ ショクバイ ニ ヨル カスイ ブンカイ カアルコール ブンカイ オヨビ アルコール ノ フカ ハンノウ
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In this accounts, we describe our recent studies on hydrolysis, alcoholysis, and addition of alcohols to organic molecules. The reactions utilizing water and alcohols as a reagent are one of the most basic and simple reactions. The palladium-catalyzed asymmetric hydrolysis and alcoholysis of vinyl ethers gave valuable axially-chiral 1,1'-bi-2-naphthol and 1,1'-bi-2-phenol derivatives and chiral P-chirogenic compounds in optically active form. The reaction is applied for hydrolytic deallylation of N-allyl amide and allyl esters. The later one was achieved by palladium/ruthenium dual catalysts which is the first example of catalytic irreversible ester hydrolysis. Gold complexes also catalyzed vinyl ether alcoholysis and hydroalkoxylation of olefins. In the later reaction, simple unactivated olefins can be used as substrates and gave the product in 92% yield. The copper-DTBM-SEGPHOS complex catalyzed alcoholysis of azlactones which is the first example showing zero-order kinetic resolution.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 68 (7), 738-744, 2010
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205311457536
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- NII論文ID
- 10026869968
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- NII書誌ID
- AN0024521X
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- COI
- 1:CAS:528:DC%2BC3cXovFKis7o%3D
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 10769751
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可