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- 宇根山 健治
- 岡山大学異分野融合先端研究コア
書誌事項
- タイトル別名
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- Unique Utilization of Fluorine(F<sub>2</sub>) as a Reaction-Activator for Organic Synthesis
- フッ素のユニークな使い方--フッ素(F2)を活性化剤として用いる有機合成化学反応
- フッソ ノ ユニーク ナ ツカイカタ フッソ F2 オ カッセイカザイ ト シテ モチイル ユウキ ゴウセイ カガク ハンノウ
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抄録
Fluorinated organic compounds have received increasing attention due to their unique biological nature in medicinal science and peerlessly excellent property in material science. And thus, a lot of methods for synthesizing highly functionalized fluorinated organic compounds and a number of suitably designed fluorinating reagents have been developed in recent years, most of which have been well documented in excellent reviews and books. However, no review on unique utilization of fluorine(F2) for functionalizing or synthesizing fluorine-free organic compounds has been published. This review involves the fluorine-promoted functionalizations such as oxidations of thiophenes to thiophene S,S-dioxides, pyridines and quinolines to the corresponding N-oxides, and amino group to nitro group along with direct hydroxylation and iodination of aromatics, epoxidation of electron-deficient alkenes, and direct functionalization of 2-position of pyridines. Almost instantaneous oxygen transfer reactions under mild conditions and effective generations of hydoxylium and iodonium ion equivalents otherwise impossible characterize the fluorine-promoted functionalizations.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 68 (7), 694-704, 2010
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205311458944
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- NII論文ID
- 10026869715
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- NII書誌ID
- AN0024521X
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- COI
- 1:CAS:528:DC%2BC3cXovFKjur0%3D
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 10769626
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可