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- 菊池 修
- 筑波大学化学系
書誌事項
- タイトル別名
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- Molecular Orbitals and O-O Cleavage of Peroxides
- カサンカブツ ノ ブンシ キドウ ト O O カイレツ ハンノウ
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The reaction mechanisms of the O-O cleavage of organic peroxides, hydrogen peroxide, hydroperoxides, dialkyl peroxides, peracids, peroxyesters, and diacyl peroxides, have been explained on the basis of their HOMO and LUMO and on the basis of the potential surfaces along the reaction paths.<BR>The discussion covers the electronic structure and conformation of the peroxides, the characteristics of HOMO and LUMO of the peroxides, the reaction with nucleophiles and with electrophiles, homolytic decomposition process, radical-induced decomposition, and the electronic structure of the radicals produced from the O-O cleavage.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 37 (8), 678-688, 1979
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205311586688
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- NII論文ID
- 130000924008
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 2061792
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可