書誌事項
- タイトル別名
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- Rhodium-Catalyzed Addition of Organometallic Reagents to Carbon-Hetero Atom and Electron Deficient Carbon-Carbon Double Bonds
- ロジウム サクタイ ショクバイ ニ ヨル ユウキ キンゾク シヤク ノ タンソ ヘテロ ゲンシ オヨビ デンシ ブソク タンソ タンソ ニジュウ ケツゴウ エ ノ フカ ハンノウ
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説明
Recent progress on the rhodium-catalyzed addition reactions of organometallic reagents to carbon-hetero atom and electron deficient carbon-carbon double bonds in such as aldehydes, ketones, imines, and α, β-unsaturated carbonyl compounds are described. The reactions are considered to involve the generation of the organorhodium intermediate by the transmetalation with the organometallic reagents, which actually adds to the substrates. A wide range of organometallic reagents such as tin, boron, silicon, lead, bismuth, titanium, and zirconium can be employed in these catalytic addition reactions. Highly enantioselective asymmetric additions have also been achieved using chiral ligands for rhodium complexes.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 61 (6), 572-582, 2003
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205311752192
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- NII論文ID
- 10011906355
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 6612912
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可