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- 冨田 育義
- 東京工業大学大学院総合理工学研究科
書誌事項
- タイトル別名
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- Creation of Diverse .PI.-Conjugated Polymers via Main Chain-reactive Organometallic Polymers
- シュサガタ ハンノウセイ ユウキ キンゾク ポリマー ノ セッケイ ト コレ オ ケイユスル タサイナ パイ キョウヤク コウブンシ ノ ソウセイ
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説明
Polymers possessing reactive organometallic repeating units in the main chain are potentially applicable to novel reactive polymers which serve as powerful synthetic precursors for various main chain-functionalized materials. Accordingly, organometallic polymers containing metallacycles such as cobaltacyclopentadiene and titanacyclopentadiene were prepared and their reactions were studied. The metallacyclopentadiene-containing polymers were prepared by the reactions of diynes with low-valent organometallic complexes. Cobaltacyclopentadiene-containing polymers are air-stable materials that can be converted into other organocobalt polymers possessing cyclobutadinecobalt and cobalticinium units and into organic polymers with diverse main chain functionality. Likewise, regioregular organotitanium polymers produced from aromatic terminal diynes and low-valent titanium complexes provide ic-conjugated organic polymers possessing unsaturated backbones in the main chain by their polymer reactions. Properties of the organometallic polymers will also be described.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 66 (5), 436-443, 2008
公益社団法人 有機合成化学協会
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390001205311862144
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- NII論文ID
- 10021174901
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 9503878
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可