アセトトルイドとクロラールの反応

DOI Web Site

書誌事項

タイトル別名
  • Reactions of Acetotoluides with Chloral
  • アセトトルイド ト クロラール ノ ハンノウ

この論文をさがす

説明

Treatment of o-, m-, and p-acetotoluide and chloral with concsulfuric acid was found to give several products. Compounds isolated were 2-methyl-5- (1, 2, 2, 2-tetrachloroethyl) acetanilide (11), 3-acetamido-p-tolualdehyde (12) and 6, 6'-dimethy1-3, 3'-dichlorovinylidene-diacetanilide (13) from the reaction of o-acetotoluide with chloral. 3-Methyl-4- (1, 2, 2, 2-tetrachloroethyl) acetanilide (15), 4- (1-hydroxy-2, 2, 2-trichloroethyl) -3-methyl acetanilide (16) and an unidentified compound (17) were isolated from the eraction of m-acetotoluide. And then 4-methyl-3- (1, 2, 2, 2-tetrachloroethyl) acetanilide (3), an unidentified compound (18), 4-methyl-3- (2, 2, 2-trichloro-1-hydroxy ethyl) acetanilide (19), 5-acetamido-o-tolualdehyde (4) and α- (5-acetamido-o-tolyl) -α-chloroacetic acid (20) were isolated from the reaction products of p-acetotoluide. The structures of these compounds were established mainly by the spectroscopic studies and the process for the formation of these compounds was illustrated in Chart 1.

収録刊行物

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ