Recent Development of Late Transition Metal Catalysts for Polymerization of Substituted Acetylenes

DOI DOI Web Site 54 References

Bibliographic Information

Other Title
  • 後周期遷移金属触媒を用いた置換アセチレン重合の新展開
  • コウシュウキ センイ キンゾク ショクバイ オ モチイタ チカン アセチレン ジュウゴウ ノ シン テンカイ
  • ChemInform Abstract: Recent Development of Late Transition Metal Catalysts for Polymerization of Substituted Acetylenes

Search this article

Description

This article overviews the new aspects of transition metal catalysts for polymerization of substituted acetylene monomers. The activity of rhodium-based catalysts is enhanced by introducing a strongly π-acidic diene ligand, tetrafluorobenzobarrelene (tfb). Precise control of polymerization of phenylacetylenes is achieved by two types of rhodium catalysts bearing tfb. The activity of zwitterionic rhodium-type catalyst is also intensified by the introduction of tfb, which achieves a higher monomer consumption rate than that with the conventional rhodium catalyst. Disubstituted acetylenes with polar functional groups are polymerized by well-defined ruthenium carbene catalyst. Phenylacetylenes having a coordinative substituent at the ortho position on its aromatic ring are efficiently polymerized by the ruthenium carbene catalyst to give the corresponding polymers in high yields.

Journal

References(54)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top