書誌事項
- タイトル別名
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- Novel Organosilicon Compounds Performing as Molecular Machines
- ケイソ ノ トクチョウ オ リヨウ シタ ブンシ キカイ ケンキュウ
- ChemInform Abstract: Novel Organosilicon Compounds Performing as Molecular Machines
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説明
A molecular machine has been defined as a discrete number of molecular components that perform mechanical-like movements in response to specific stimuli. In this account, we describe synthesis and dynamics of novel organosilicon compounds working as molecular machines. The introduction of the clutch-declutch mechanism into a molecular gear system was achieved using interconversion between silane and silicate. Molecular gyroscopes having a phenylene rotator encased in three long siloxaalkane spokes were synthesized; the merits of siloxaalkane chains, which are easily constructed and chemically stable and exhibit good crystallinity, are exerted in the synthesis. The silicon-based directed synthesis of [2]rotaxanes without polar functional groups is described.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 68 (9), 930-938, 2010
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205312882816
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- NII論文ID
- 10026870718
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 15222667
- 00379980
- 09317597
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- NDL書誌ID
- 10821087
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- 本文言語コード
- ja
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- データソース種別
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- NDLサーチ
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- 抄録ライセンスフラグ
- 使用不可