Synthesis of Polymers with Well-defined Structures by Novel Ring-opening Reactions of Oxetanes
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- Nishikubo Tadatomi
- Department of Materials and Life Chemistry, Kanagawa University
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- Kameyama Atsushi
- Department of Chemistry, Faculty of Engineering, Kanagawa University
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- Kudo Hiroto
- Department of Materials and Life Chemistry, Kanagawa University
Bibliographic Information
- Other Title
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- オキセタン化合物の新規開環反応による構造制御された高分子の合成
- オキセタン カゴウブツ ノ シンキカイカン ハンノウ ニ ヨル コウゾウ セイギョ サレタ コウブンシ ノ ゴウセイ
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Abstract
This article reports new ring-opening reactions of oxetane compounds with certain reagents such as acyl chlorides, carboxylic esters, phenols, and carboxylic acids using certain quaternary onium salts as catalysts. Reaction behavior of oxetanes was investigated based on kinetic study. These new reactions of oxetanes were also successfully applied to polymer synthesis. Polymers containing pendant reactive groups were obtained by polyaddition of bis (oxetane) s with certain difunctional monomers such as dicarboxylic chlorides, bis (phenol) s, or dicarboxylic acids. The reaction of oxetanes with cyclic carboxylic anhydrides proceeded in alternating ring-opening copolymerization mode to give copolymers with A-B sequence. The authors found new anionic ring-opening polymerization of oxetanes containing pendant hydroxyl groups using appropriate catalyst system. Hyperbranched polymers containing hydroxyl groups were prepared by the reactions of oxetanes. Alkali developable photopolymers were also obtained by the chemical modification of the hyperbranched polymers. The reactions of oxetanes with certain reagents were also useful for thermal curing reaction providing oxetane resins.
Journal
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- Journal of Synthetic Organic Chemistry, Japan
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Journal of Synthetic Organic Chemistry, Japan 64 (9), 934-946, 2006
The Society of Synthetic Organic Chemistry, Japan
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Details 詳細情報について
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- CRID
- 1390001205312890880
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- NII Article ID
- 10018052377
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- NII Book ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL BIB ID
- 8091395
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed