Study of Photo-oxidation with Molecular Oxygen
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- Hirashima Shin-ichi
- Gifu Pharmaceutical University
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- Itoh Akichika
- Gifu Pharmaceutical University
Bibliographic Information
- Other Title
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- 分子状酸素を利用する光酸化反応の開発
- ブンシジョウ サンソ オ リヨウスル ヒカリ サンカ ハンノウ ノ カイハツ
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Abstract
Molecular oxygen has recently received much attention, since it is photosynthesized by plants and is an effective oxidant of larger atom efficiency than that of other oxidants. In the course of our study of photo-oxidation, we have found that alcohols and methyl group at aromatic nucleus were oxidized directly to the corresponding carboxylic acids in the presence of catalytic bromine sources, such as lithium bromide, bromine, and hydrobromic acid, in an oxygen atmosphere under irradiation of UV or VIS. This new oxidation reaction is interesting in keeping with the notion of Green Chemistry due to non-use of heavy metals, waste reduction, use of molecular oxygen, and inexpensive acquisition of reagents. Herein, we report our study on the generality of this aerobic photo-oxidation in detail.
Journal
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- Journal of Synthetic Organic Chemistry, Japan
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Journal of Synthetic Organic Chemistry, Japan 66 (8), 748-756, 2008
The Society of Synthetic Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001205313138304
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- NII Article ID
- 10024278061
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- NII Book ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL BIB ID
- 9619059
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed
