Thermal Reaction of Methyl Linoleate in the Presence of Iodine

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  • ヨウ素の存在下におけるリノール酸メチルの加熱反応
  • ヨウソ ノ ソンザイカ ニ オケル リノールサン メチル ノ カネツ ハンノウ
  • on the Hydrogen Source Required for the Formation of Methyl Octadecenoates
  • オクタデセン酸メチルの生成に必要な水素源について

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Methyl octadecenoates are formed by thermal reaction of methyl linoleate in the presence of iodine. For the purpose of clarification of hydrogen source required for the formation of octadecenoates, quantitative relationship of reaction products was studied by the methods of fractional distillation, mass spectral and GLC analyses, and of the measurement of UV spectra of the reaction products after hydrogenation. <BR>The results showed that hydrogen iodide evolved by the action of iodine on Diels-Alder adduct type dimers makes an important role as hydrogen source for the formation of octadecenoates.

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