テルペン類の銅-亜鉛系触媒による減圧下気相異性化, 脱水素反応に関する研究 (第7報)

DOI Web Site Web Site

書誌事項

タイトル別名
  • Studies on the Isomerization and Dehydrogenation with the Catalyst Systems Composed of Copper and Zinc under a Reduced Pressure of Terpenes. VII.
  • テルペンルイ ノ ドウ アエンケイ ショクバイ ニヨル ゲンアツカ キソウ イ
  • The Isomerization and Dehydrogenation of Acyclic Terpenes and Alicyclic Alcohols with the Catalyst Systems Composed of Copper and Zinc under Reduced Pressure
  • 鎖状テルペン類および脂環式アルコールの銅-亜鉛系触媒による減圧下気相異性化, 脱水素反応

この論文をさがす

説明

Acyclic terpenes and alicyclic alcohols were isomerized and dehydrogenated with catalyst systems composed of copper and zinc over a temperature range from 160 to 262°C under a reduced pressure.<BR>Geranial, neral, citronellal, dihydrocitronellal, myrcene, and homoperillyl alcohol were obtained by the isomerization and dehydrogenation of geraniol [1], nerol [2], citronellol [3], dihydrocitronellol [4], 2- (10) -pinene [5], and nopol [6], respectively.<BR>In addition, dehydrogenation of alcohols, such as cyclopentanol [7], cyclohexanol [8], 2-methylcyclohexanol [9], and cyclooctanol [10] gave corresponding alicyclic oxo-compound in almost quantitative yields.<BR>The most suitable conditions for the reactions mentioned above were proposed in the light of the experimental results.

収録刊行物

  • 油化学

    油化学 24 (10), 654-658, 1975

    公益社団法人 日本油化学会

詳細情報 詳細情報について

問題の指摘

ページトップへ