書誌事項
- タイトル別名
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- Synthesis and Utilization of Fluorinated Carboxylic Acid Derivatives. V.
- ガン フッソ シボウサン ユウドウタイ ノ ゴウセイ ト リヨウ 5 N ペル
- Preparation and Properties of <I>N</I>- (perfluoroacyl) ethylenediamine Ethylene Oxide Adduct
- <I>N</I>- (ペルフルオロアシル) エチレンジアミン・エチレンオキシド付加体の合成とその性質
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抄録
The addition of ethylene oxide (EO) to N- (perfluoroacyl) ethylenediamine (N F) in the presence of Rf =n-C3F7 or n-C7F15 in benzene was carried out at 50130°C in an autoclave without catalysts. The addition reaction proceeded easily and stepwise to yield 1 : 1 and 2 : 1 adducts at low temperature. There products were isolated and measured by gel permeation chromatography. The rate of addition was higher at higher concentration of EO. When the reaction was carried out at [EO] / [NF] =12 at 8090°C for 5 hours, yield of the 2 : 1 adduct was 98%. <BR>Above 90°C, the marked formation of byproducts occurred. <BR>The surface activity of the adduct with Rf =n-C7F15-was found better than that with Rf =n-C3F7.
収録刊行物
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- 油化学
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油化学 37 (2), 102-107, 1988
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390001205333883904
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- NII論文ID
- 130001020233
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- NII書誌ID
- AN00245435
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- ISSN
- 0513398X
- 18842003
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- NDL書誌ID
- 3170093
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可