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- 前田 瑞夫
- 九州大学工学部
書誌事項
- タイトル別名
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- Surface Template Polymerization
- カイメン イガタ ジュウゴウホウ ブンシ イガタ オ モツ ジュシ ノ アタラ
- A New Preparation Method to Molecularly Imprinted Resins
- 分子鋳型をもつ樹脂の新しい合成法
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説明
Template polymerization has been used to prepare polymeric materials for applications in molecular recognition. However, since the conventional one is conducted in the bulk from monomer, some problems arise ; e.g., slow rebinding kinetics and limited applicability to a water-soluble guest. We designed template polymerization at an oil-water interface. A surfacetemplated resin was prepared by an emulsion polymerization using oleic acid as a host monomer, divinylbenzene (DVB) as a resin matrix-forming monomer, and Cu2+ ion as the target. A phosphate-carrying surface-templated resin can be prepared as well. Another surface imprinting technique was developed based on a surface-carboxylated latex particle, which was swollen with DVB. The surface-mobile groups were reorganized through complexation with the target on the surface and then immobilized by crosslinking of DVB. These two methods can imprint the template structure on a resin surface, resulting in the rapid, reversible and unusually strong complexation with the target.
収録刊行物
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- 油化学
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油化学 43 (11), 921-926, 1994
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390001205334436224
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- NII論文ID
- 10006947335
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- NII書誌ID
- AN00245435
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- ISSN
- 0513398X
- 18842003
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- NDL書誌ID
- 3905648
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- データソース種別
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- JaLC
- NDL
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- 使用不可