Crossed Aldol Condensation Reactions between Various Aldehydes and Acetone Using Solid Base Catalysts

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  • KURATA Takeo
    Department of Industrial Chemistry, Faculty of Science and Engineering, Meiji University
  • FUYA Takeshi
    Department of Industrial Chemistry, Faculty of Science and Engineering, Meiji University

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  • 固体塩基触媒を用いた各種アルデヒドとアセトンとの交差アルドール縮合反応
  • コタイ エンキ ショクバイ オ モチイタ カクシュ アルデヒド ト アセトン

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Abstract

Crossed aldol condensation reactions between various aldehydes (saturated fatty aldehydes, unsaturated aldehydes and terpene aldehydes) and acetone using solid base catalysts were studied.<BR>Ca (OH) 2, Sr (OH) 2·8H2O and Ba (OH) 2·8H2O were found to be very effective for the crossed aldol condensation reactions. The various aldehydes were converted to their corresponding α, β-unsaturated ketones.

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