LB膜による光電変換

藤平 正道

doi:10.5650/jos1956.39.3_148

LB膜による光電変換

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藤平正道

東京工業大学・工学部生体分子工学科

書誌事項

タイトル別名

Photoelectric Conversion by LB Film Monolayer Assemblies
LB マクニヨルコウデンヘンカン

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抄録

Simulation of photoelectric conversion in the photosynthetic reaction center by monomolecular layer assemblies of a folded or a linear type A-S-D triad carried out in this laboratory is reviewed. The oriented triad molecule acts as a charge separation unit and is named a molecular photodiode. The combined system with the linear triad and an antenna pigment is discussed next in terms of the charge separation and the light harvesting. Finally, electrocatalytic reduction of CO₂ by alkyl Ni²⁺-cyclam derivatives studied is described. This monolayer can be used in artificial photosynthetic LB films as a catalytic layer which is deposited upon the electron-acceptor side of the charge separation layer in series.