生理活性物質の合成に関する研究 (第11報)

DOI Web Site Web Site 被引用文献6件 参考文献9件

書誌事項

タイトル別名
  • Synthesis of Physiologically Active Substance. XI.
  • セイリ カッセイ ブッシツ ノ ゴウセイ ニカンスルケンキュウ 11 アルファ
  • Synthesis and Insecticidal Activity of α- and β-Campholenic Pyrrolidinamides and Piperidinamides
  • α-およびβ-カンフォレニルピロリジンアミドおよびピペリジンアミド類の合成と殺虫活性

この論文をさがす

抄録

α- and β-Campholenic nitriles (1a), (2a) were prepared by various methods and converted to campholenic acid chlorides by hydrolysis and chlorination. The chlorocarbonylated campholenes were condensed with pyrrolidine, piperidine, 2-, 3-, or 4-methylpiperidines, and 2, 6- or 3, 5-dimethylpiperidines to obtain amide compounds (3) (16) in 3264 % yields in five steps, the first being imidation of α-pinene or camphor.<BR>Insecticidal activity of amide compounds (3) (16) toward Tyrophagus putrescentiae, Dermatophagoides farinae, Culex pipiens pallens, Musca domestica Linne and Blattella germanica were measured. On filter paper, amide compounds (3) (16) from (1) and (2) showed greater insecticidal activity than N, N-diethyl-m-toluamide for T. putrescentiae and D. farinae.<BR>Toward T. putrescentiae, amide compounds (3) (16) at 1.0 g/m2 expressed insecticidal activity from 75100 %, this range exceeding that of commercial isobornyltiocyano acetic acid. At 1.0 g/m2 for these amide compounds (3) (16), D. farinae was almost eliminated.

収録刊行物

  • 油化学

    油化学 44 (4), 309-315, 1995

    公益社団法人 日本油化学会

被引用文献 (6)*注記

もっと見る

参考文献 (9)*注記

もっと見る

詳細情報 詳細情報について

問題の指摘

ページトップへ