Acylation Reaction of Δ<SUP>2</SUP>-Carene and Δ<SUP>3</SUP>-Carene in the Presence of Synthetic Zeolites

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  • NOMURA Masato
    Department of Industrial Chemistry, Faculty of Engineering, Kinki University
  • HISATOMI Satoshi
    Department of Industrial Chemistry, Faculty of Engineering, Kinki University
  • HAMADA Toshimasa
    Department of Industrial Chemistry, Faculty of Engineering, Kinki University
  • FUJIHARA Yoshihito
    Department of Industrial Chemistry, Faculty of Engineering, Kinki University

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Other Title
  • 合成ゼオライト存在下でのΔ<SUP>2</SUP>-カレンおよびΔ<SUP>3</SUP>-カレンのアシル化反応
  • ゴウセイ ゼオライト ソンザイカ デ ノ デルタ 2 カレン オヨビ デルタ
  • Reaction of Terpens in the Presence of Synthetic Zeolites (Part 23)
  • テルペン類の合成ゼオライトを触媒とする反応に関する研究 (第23報)

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Examination was made of the acylation reactions of Δ2-carene (1) and Δ3-carene (2) with acid anhydrides (acetic anhydride and propionic anhydride) in the presence of synthetic zeolites.<BR>The following results were obtained : In acetic anhydride and propionic anhydride with Y Type zeolites, the acylation of (1) gave 2-acetyl-3-carene (3) and 2-propionyl-3-carene (4) respectivery. In Y type Zeolites, 4-acetyl-2-carene (5) and 4-propionyl-2-carene (6) were obtained from (2) as the main products, respectively.

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