Synthesis and Properties of α, ω-Bisamidobetaine-type Amphoteric Surfactants from Long-chain Dibasic Acids

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  • 長鎖二塩基酸からのα, ω-ビスアミドベタイン型両性界面活性剤の合成と性質
  • チョウサ 2エンキサン カラ ノ アルファ オメガ ビスアミドベタインガタ リ

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Abstract

α, ω-Type amphoteric surfactants containing bisbetaine groups were synthesized by reactions of alkanedioic acids with N, N-dimethyl-1, 3-propanediamine, followed by quaternization of the resulting bisaminoamides with sodium chloroacetate. The latter process was carried out in water or a mixture of isopropyl alcohol and water using sodium hydrogencarbonate or sodium hydroxide as the catalyst.<BR>The properties of the α, ω-bisamidobetaine in aqueous solution were studied. α, ω-Bisamidobetaines derived from hexadecanedioic and icosanedioic acid showed good catalytic activity for the halide displacement reaction and a excellent ability to bring about lime soap dispersion.

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