Role of partitioning of elements between solid solution mineral and aqueous solution for migration of radionuclides from high level nuclear waste

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  • 高レベル放射性廃棄物からの核種移行に対する固溶体鉱物-水溶液間の元素分配の役割
  • コウレベル ホウシャセイ ハイキブツ カラノ カクシュ イコウ ニ タイスル コヨウタイ コウブツ スイヨウエキカン ノ ゲンソ ブンパイ ノ ヤクワリ

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  Experimental studies on the partitioning of minor elements between carbonate and aqueous solution were summarized in order to elucidate the partitioning of radioactive elements migrating from high level nuclear waste to geologic environment between carbonate and aqueous solution. The relationships among the partition coefficient, solubility product and solubilitytheoretically derived. The factors causing derivation of the experimental partition coefficients from theoretical ones (diffusion, (were) reaction rate, physical properties of solid solution) were considered. The relationship between the partition coefficients and ionic radii suggests that physical factors of solid solution are important for determining the partition coefficient values.

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