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- 浅野 圭佑
- 京都大学大学院工学研究科
書誌事項
- タイトル別名
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- Asymmetric Syntheses Utilizing Mild Activations by Organocatalysts
- オンワ ナ ユウキ ショクバイ ガ モタラス セイミツ フセイ ゴウセイ
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抄録
<p>Organocatalysts utilize various molecular interactions for catalysis. However, molecular interactions for organocatalysis are in general not as strong as those for metal-catalysis. Thus, because of this character, multiple activations are often necessary to catalyze a reaction, however, in other words, it enables the use of multipoint interactions in the transition state of a catalytic reaction, thereby leading to high stereoselectivity, even if it is a very rapid reaction. On the basis of this concept, we developed asymmetric reactions affording various heterocycles via organocatalytic hetero-Michael additions and the applied synthetic transformations. In order to accomplish high enantioselectivity, we designed reactions utilizing different activation manners by organocatalysts depending on the substrate type; it is a key to utilize simultaneous multipoint interactions between a catalyst and a substrate.</p>
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 74 (12), 1194-1205, 2016
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205338892544
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- NII論文ID
- 130005251191
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 027791209
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可