Synthesis and Application of Novel Functional Molecules by Inner and Outer Control of Fullerenyl Cage Focused on the Spherical Reaction Sites
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- Kokubo Ken
- Graduate School of Engineering, Osaka University
Bibliographic Information
- Other Title
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- 球面反応場に着目したフラーレンケージ内外の制御による新規機能分子の創製と応用
- キュウメン ハンノウジョウ ニ チャクモク シタ フラーレンケージ ナイガイ ノ セイギョ ニ ヨル シンキ キノウ ブンシ ノ ソウセイ ト オウヨウ
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Description
Various types of functionalized fullerenes have been widely developed by considering unique reactivities of the spherical reaction sites; such as not only the enhanced reactivity due to the curved and thus strained C=C double bonds, but also the multiple addition and its electronic control for the selective monoaddition, the regioselectivity controls by spherical π-conjugation and by twisted C=C double bond, the unprecedented substitution mechanism, the highly symmetrical multiple addition via fullerene anion, and the drastic reactivity change by ion encapsulation. The derivatives also proved effective against many potential applications to CMP polishing slurry, antioxidant, anti-inflammatory agent, resist materials, n-type materials for organic photovoltaics, and more.
Journal
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- Journal of Synthetic Organic Chemistry, Japan
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Journal of Synthetic Organic Chemistry, Japan 72 (12), 1348-1359, 2014
The Society of Synthetic Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001205339458304
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- NII Article ID
- 130004749131
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- NII Book ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL BIB ID
- 025959825
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed