Unique Reaction in Bacterial Terpene Indole Biosynthesis
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- Awakawa Takayoshi
- Graduate School of Pharmaceutical Sciences, The University of Tokyo
Bibliographic Information
- Other Title
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- テルペンインドール化合物テレオシジンの生合成反応
- テルペンインドール カゴウブツ テレオシジン ノ セイゴウセイ ハンノウ
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Description
<p>Teleocidin B is a terpene indole isolated from bacteria. A methyltransfer enzyme in teleocidin B biosynthesis, TleD not only installs a methyl group on the geranyl moiety of the precursor, but also facilitates the nucleophilic attack from the electron-rich indole to the resultant cation, to form indole-fused cyclohexene ring. This study reports novel biosynthetic reaction in the field of terpene cyclization.</p>
Journal
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- Journal of Synthetic Organic Chemistry, Japan
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Journal of Synthetic Organic Chemistry, Japan 76 (5), 410-413, 2018-05-01
The Society of Synthetic Organic Chemistry, Japan
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Details 詳細情報について
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- CRID
- 1390001205339506304
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- NII Article ID
- 130006733948
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- NII Book ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL BIB ID
- 029057584
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed