書誌事項
- タイトル別名
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- Development of Synthetic Methodologies for Heterocycles Using Diene-transmissive Hetero-Diels-Alder Reaction
- ジエン デンタツ ヘテロ Diels-Alder ハンノウ オ リヨウ シタ フクソカン ゴウセイホウ ノ カイハツ
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説明
<p>The diene-transmissive hetero-Diels-Alder reaction (DTHDA reaction) is a special case of the DTDA reaction in which one or more heteroatoms are contained within either a cross-conjugated triene/polyene (heterodendralene) π-system, a dienophile π-system or both. Therefore, the DTHDA protocol is an efficient and attractive method for the stereoselective synthesis of a variety of heterocyclic systems. Merits and potential of the DTHDA methodology for heterocyclic synthesis can be widely extended by structural variations and complexity of both diene and dienophile; the kind, numbers, and positions of heteroatoms contained in either the cross-conjugated triene/polyene ([3/n] heterodendralene) or the dienophile framework, as well as the inter- or intramolecular cycloaddition mode, and its predictable regio- and stereoselectivities. In this paper, we introduce the synthesis of a variety of heterocycles using the DTHDA reaction with a focus on our research.</p>
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 74 (8), 803-813, 2016
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205341224448
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- NII論文ID
- 130005261223
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 027552817
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- 本文言語コード
- ja
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