書誌事項
- タイトル別名
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- Influence of Mechanochemical Treatment of Lime-Silica Mixtures on Gyrolite Formation
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説明
Gyrolite (Ca8Si12O30 (OH) 4·7H2O) was hydrothermally prepared in a stirred suspension at 180°Cusing mechanochemically treated starting mixtures of lime and amorphous precipitated silica at the theoretical Ca/Si ratios of 0.67 for gyrolite and 0.50 for the Zphase. The starting materials were treated by planetary ball milling for 15 min to 8 h at room temperature. With increased milling time, Ca (OH) 2reacted with silica to make a C-S-H like phase having a broad XRD peak centered at 0.30 nm. The C-S-H like phase contained a partly sheet-like silicate anion structure. Using the mechanochemically prepared mixture, with a Ca/Si=0.50 the hydrothermal reaction sequence is mechanochemically formed C-S-H→Assarsson's Z-phase→gyrolite and with a Ca/Si=0.67 mechanochemically formed C-S-H→gyrolite. However, using the mixtures at Ca/Si=0-67 without milling, the sequence is CaO+silica→hydrothermally formed C-S-H→gyrolite.
収録刊行物
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- Journal of the Society of Inorganic Materials, Japan
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Journal of the Society of Inorganic Materials, Japan 8 (291), 104-109, 2001
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詳細情報 詳細情報について
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- CRID
- 1390001205389756032
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- NII論文ID
- 130003821313
- 10006095929
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- NII書誌ID
- AA11416367
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- ISSN
- 13453769
- 21854378
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- NDL書誌ID
- 5694016
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- データソース種別
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- JaLC
- NDL
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可